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In this post I am not asking for help. Instead, I want to post it here in case anyone out there is managing their site via Acquia Dev Desktop.
After (quite) some pain, searching, trial and error, I have managed to update Drupal core (8.6.13). My site was built and is managed via Acquia Dev Desktop. I had tried various update methods, manual, composer, etc, each time getting errors. Finally I found a few posts and pieced it together how I was able to update D core. Leave it here in case anyone will bang their head into the wall as well.
When upgrading from 8.5.x to 8.6.14 I get this message:
Warning: Class Drupal\Core\Extension\Extension has no unserializer in Drupal\Core\Cache\DatabaseBackend->prepareItem() (line 167 of core/lib/Drupal/Core/Cache/DatabaseBackend.php).