Allowed memory size of 25165824 bytes exhausted & You have an error in your SQL syntax

Fatal error: Allowed memory size of 25165824 bytes exhausted (tried to allocate 1451877 bytes) in C:\E\AppServ\www\d6\includes\common.inc on line 2293

user warning: You have an error in your SQL syntax; check the manual that corresponds to your MySQL server version for the right syntax to use near ':242:s:2:"af";s:11:"Afghanistan";s:2:"ax";s:13:"Aland Islands";s:2:"al";s:7:"Alb' at line 1 query: UPDATE a:242:s:2:"af";s:11:"Afghanistan";s:2:"ax";s:13:"Aland Islands";s:2:"al";s:7:"Albania";s:2:"dz";s:7:"Algeria";s:2:"as";s:14:"American Samoa";s:2:"ad";s:7:"Andorra";s:2:"ao";s:6:"Angola";s:2:"ai";s:8:"Anguilla";s:2:"aq";s:10:"Antarctica";s:2:"ag";s:19:"Antigua and Barbuda";s:2:"ar";s:9:"Argentina";s:2:"am";s:7:"Armenia";s:2:"aw";s:5:"Aruba";s:2:"ac";s:16:"Ascension Island";s:2:"au";s:9:"Australia";s:2:"at";s:7:"Austria";s:2:"az";s:10:"Azerbaijan";s:2:"bs";s:7:"Bahamas";s:2:"bh";s:7:"Bahrain";s:2:"bd";s:10:"Bangladesh";s:2:"bb";s:8:"Barbados";s:2:"by";s:7:"Belarus";s:2:"be";s:7:"Belgium";s:2:"bz";s:6:"Belize";s:2:"bj";s:5:"Benin";s:2:"bm";s:7:"Bermuda";s:2:"bt";s:6:"Bhutan";s:2:"bo";s:7:"Bolivia";s:2:"ba";s:22:"Bosnia and 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